(1) Whitney Approximation Theorem: Every continuous map f \colon M \to N between smooth manifolds is homotopic to a smooth map.
(2) Sard Theorem: Let f \colon M \to N be a smooth map between smooth manifolds, and let \operatorname{Crit}(f) be the locus of points of M where the differential df has rank < \dim(N). Then the image of \operatorname{Crit}(f) has zero Lebesgue measure in N. In particular, if \dim(M) < \dim(N) then f cannot be surjective.
Given a continuous loop c \colon [0, \, 1] \to \mathbb{S}^n, we want to show that c is homotopically trivial. By (1), it is not restrictive to assume that c is piecewise smooth. Then, by (2), c cannot be surjective (recall that we are assuming n \geq 2).
Now, take a point p not in the image of c. Then we can see c as a loop in \mathbb{S}^n-\{p\}, which is a contractible space (it is homeomorphic to \mathbb{R}^n via the stereographic projection). So c is homotopically trivial.
Remark. The regularization provided by (1) is essential here. In fact, there exist continuous, non-smooth loops "of Peano type", whose image is the whole sphere.